Highly dispersible cerium-oxide modified Ni/SBA-15 for steam reforming of bio-mass based JP10

摘要

Ni/SBA-15 modified by highly dispersed cerium-oxide was prepared with the aid of sucrose for steam reforming of JP10(C_(10)H(16)).Their characterization showed that addition of appropriate amount ceria led to the formation of highly dispersed CeO_(2)and Ni,and the CeO_(2)covered smaller nickel particles like strawberry seeds to form much more interface between them.Their catalytic activity exhibited higher stability over time on stream of 6.5 h with conversion higher than 95%and higher carbon resistance(mass loss less than 4.5%by TG),which may derive from good properties below:(1)much more interface enhanced cooperation effect and increased turnover frequency at the interface;(2)the stronger interaction between Ni and ceria to suppress sintering by formation of Ni-O-Ce solid solution;(3)the large amount of oxygen vacancies from the formation of Ni-O-Ce solid solution and highly dispersed CeO_(2)to facilitate the water-gas-shift reaction and carbon removal.