Os络合物催化烯烃加氢和异构化反应

摘要

综述了近年来锇络合物用于催化烯烃加氢和异构化反应的研究进展。 Os催化剂在H2分子和转移加氢二个方面用于烯烃加氢反应均表现出较高的活性和选择性。因此它有望成为有机合成中的一个强有力的工具。%This review focuses on the evolution of the use of osmium complexes as catalysts in the hydrogena‐tion and isomerization of olefins. Osmium systems show good catalytic activities and selectivities in the hydrogenation of olefins via both dihydrogen and transfer hydrogenation. Such systems there‐fore have significant potential to become a powerful tool in organic synthesis.