Synthesis,characterization and hydrogen storage capacity of MS2 (M - Mo,TI) nanotubes

摘要

The structure,morphology and hydrogen-storage capacity of MS2 (M = Mo,Ti) nanotubes prepared by different experimental methods were studied.It was found that the MoS2 nanotubes treated by KOH displayed the gaseous storage capacity of 1.2 wt% hydrogen (under the hydrogen pressure of 3 MPa and 25℃) and the electrochemical discharge capacity of 262 mAh/g (at the discharge current density of 50 mA/g and 25℃) that corresponds to about 1.0 wt% hydrogen.In comparison,TiS2 nanotubes can store 2.5 wt% hydrogen under the hydrogen pressure of 4 MPa and 25℃,The results show that MS2 compound nanotubes are promising materials for hydrogen storage.