Electrically conductive composites were prepared via the chemical oxidative polymerization of the pyrrole monomer in polystyrene (PS) and zinc neutralized sulfonated polystyrene (Zn-SPS) films under supercritical carbon dioxide (SC-CO2) conditions.The strong swelling effect of SCCO2 made polypyrrole (PPy) particles not only form on the surface,but also become incorporated into the film,resulting in a homogeneous structure with a relatively higher conductivity.By comparison,the composite prepared in aqueous solutions shows a skin-core structure and a conductivity of 3 to 4 orders of magnitude lower than that of the former due to the diffusion-controlled process of the pyrrole monomer.The percolation thresholds of PS/PPy and Zn-SPS/PPy composites were 6.2% and 2.7% of the volume fraction of PPy,respectively,much lower than the theoretically predicted value of 16%.Moreover,the conductive composites prepared under SC-CO2 conditions showed higher thermal stability,especially in the high-temperature region.
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机译:The preparation and the in-vitro pharmacodynamics study of the intracapsular sustained-release preparations for the prevention of posterior capsule opacification
机译:神父市政厅,宗教自由和天主教传统。真实地狱中的均一教义发展案例,阿巴耶·圣马德琳(Les Barroux),第二版。修订和扩充,1998年,T。I,系统学,第一期:Preparations,LX + 466页。第二期:成果,278页。 T. II,编年史,总理专着:资料来源,第594页。第二期:所附文件,430页。 T. III,按字母顺序,第一期:参考书目,552页。第二期:一般分析索引,540页。