脱氢枞酸芳环改性的研究进展

摘要

脱氢枞酸是由歧化松香分离提纯得到的一种树脂酸,芳环是其特征结构,同其它芳香族化合物一样,可以进行多种亲电取代反应,合成抑菌剂、抗氧剂、荧光衍生试剂等.本文全面综述了近10年对脱氢枞酸芳环的改性研究,主要包括傅克反应、溴代、硝化等亲电取代反应,以及基于硝化取代产物合成含氮杂环、芳胺和酚、醌等系列衍生物,并展望了未来的改性研究趋势.%Dehydroabietic acid, the aromatic derivative of rosin, can be isolated from disproportionated rosin. Due to the presence of the aromatic ring, dehydroabietic acid could be a promising starting material for the synthesis of antibacterial agents, antioxida-nts, fluorescenc derivatizing reagents, and so on by introducing of suitable substituents into the molecule. The progress on modification research was reviewed based on aromatic ring of dehydroabietic acid in recent ten years, including electrophilic substitution reactions such as Friedel-Crafts reaction, brotnation, nitration, and some derivatives of nitrogen heterocyclic, arylamine, phenol and quinone compounds synthesized via nitration. Finally, the future tendency of modification research based on aromatic ring of dehydroabietic acid is prospected.