Hydrogen energy is one of the most useful energy in the world, and the primary problem is how to produce hydrogen effectively and continuously. The low-cost electrocatalysts with high perform-ance and stability for hydrogen evolution reaction ( HER) play an important role for improving hydro-gen production technologies. In this paper, the development of Ni-related electrocatalysts for HER was reviewed. The study on nickel oxides, double oxides/hydroxides, seleniums, and sulfides were mainly focused. The synthesis, characterization, catalytic activity, durability and the relationship between the structure and performance were also discussed.%氢能是目前世界上公认的清洁能源之一,如何有效的可持续的产氢是人们步入氢能社会首要解决的问题.研发低成本,高性能,高稳定性的电催化析氢催化剂对提升产氢技术,促进氢能经济的发展具有重要意义.本文综述了近几年发展的镍基电催化析氢催化剂,重点介绍了镍的氧化物,镍的双层氧化物/氢氧化物,硒化物,硫化物等电催化析氢催化剂的研究和发展情况,对它们的合成方法、结构特性、催化活性、稳定性能以及微观结构和析氢性能之间的关系进行深入的探讨,并一一举例说明.
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