Pd（PPh3）2Cl2催化脂肪酸脱羰端烯化反应机理初探

摘要

The reaction mechanism of decarbonylation of aliphatic acids to 1-alkenes by Pd(PPh3)2Cl2, which involues formation ofmixed anhydride, oxidation addition, insertion and antiinsertion, displacement of ligands, is suggested according to theexperimental finding and primary reaction of Pd(II) complexs catalyst.