Fe3 + Doped Bi2MoO6 photocatalyst was successfully synthesized via a hydrothermal process using Bi(NO3)3,NH4)6 Mo7O24 · 4H2O and Fe(NO3)3 as starting materials. XRD,FE-SEM and UV-Vis absorption spectrum techniques were characterized. Rhodamine B was selected as a model pollutant and to investigate the photocatalytic activity of as-synthesized sample. Thiophene was selected as a typical sulfur-containing pollutant to simulate fuel to evaluate the photocatalytic oxidative desulfurization ( Photo-Cat-ODS) activity of as-prepared sample. Results showed that Fe3+ doping caused the grain size decreasing and specific surface area increasing. UV-Vis absorption spectrum indicated that the absorption edge of Fe + doping Bi2MoO6 photocatalyst red shift. The photocatalytic activity of as-synthesized samples depend on the concentration of Fe element doping. When the doping content is 0. 5% , the photocatalyst showed the best photocatalytic activity. When using the Fe + doping Bi2MoO6 as photocatalyst and irradiation for 3 h, simulation gasoline of the sulfur reduce to 70 μg/g, desulfurization rate of reached 89%.%以钼酸铵、硝酸铋和硝酸铁为原料,采用水热/溶剂热法合成了铁掺杂的钼酸铋光催化剂,用X-射线粉末衍射、扫描电镜及紫外-可见吸收光谱等进行表征,并以罗丹明B为模型污染物,考察了纳米钼酸铋对罗丹明B溶液的光催化降解活性；以噻吩作为典型的含硫污染物,评价样品的光催化氧化脱硫活性.结果表明,Fe元素掺杂导致Bi2 MoO6的尺寸下降,比表面积增大；Fe掺杂,Bi2 MoO6吸收边发生红移；光催化活性与Fe元素的掺杂浓度有关,当掺杂量为0.5％时,活性最高；Fe掺杂Bi2MoO6对模拟汽油具有较好的脱硫活性,模拟可见光照射3h,可使用模拟汽油的硫含量降低至70 μg/g以下,脱硫率达到89％.
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