在间歇式微型反应釜中，以W-SBA-15为吸附剂，含有喹啉的十二烷溶液为模拟油，进行静态吸附脱除油品中碱性氮化物的试验，研究其吸附脱氮工艺条件及性能。结果表明，W-SBA-15最佳吸附温度为140℃，适宜的剂油质量比1∶30 g/g，适宜的吸附时间为30 min，此时的吸附量为25.66 mg/g，脱氮率为66.32%；吸附动力学可用准二级动力学方程表示为：qt =t/（0.023+0.0383t）；吸附等温线是典型的化学吸附曲线，可用Langmuir等温吸附式表示为：Qe =14.31Ce/（1+0.5549Ce ）。%With W-SBA-15 zeolite adsorbent,static adsorption respectively removes of basic nitrogen com-pounds in oil test that studies nitrogen adsorption process conditions and performance in the micro-batch reactor. The results show that the optimum temperature of basic nitrogen compounds adsorbed on the W-SBA-15 is 140℃;the suitable ratio of quality for adsorbent and oil is 1∶30 g/g;the suitable adsorption time is 30 min;now the capacity of adsorption is 25. 66 mg/g,and the rate of denitrogenation is 66. 32%;The adsorption kinetics can be used as a quasi-two kinetic equation:qt =t/(0. 023+0. 038 3t);The ad-sorption isothermal is the chemical adsorption curve which can be described by Langmuir:Qe =14. 31Ce/(1+0. 554 9Ce).
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