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KBPh4由水到系列水 -醇混合溶剂的迁移自由能

     

摘要

The standard transfer Gibbs energies (Δ trG° )of KBPh4 from reference solvent of water to water/ethanol, water/propanol, water/2-propanol,water/ethylene glycol, water/glycerol mixtures in different proportional ratio have been studied. The interactions of KBPh4 with the above mixed solvents were analyzed. The standard transfer Gibbs energy of cavity(Δ trG° cav) and the standard transfer Gibbs energy of interaction(Δ trG° int) from water to water/2-propanol mixtures at 298.15 K were calculated by the Scaled Particle Theory (SPT).

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