A series of white polymer light-emitting diodes （WPLEDs） each with a single emitting layer using ionic iridium complex is fabricated.The white light is obtained via two complementary colors of orange light emitter ionic iridium complexe [（npy）2Ir（c-phen）]PF6 （Hnpy：2-（naphthalen-1-yl）pyridine,c-phen：1-ethyl-2-（9-（2-ethylhexyl）-9H-carbazol-3-yl）-1H-imidazo[4,5-f][1,10]phenanthroline） and sky-blue light emitter Firpic （iridium bis（2-（4,6-difluorophenyl）-pyridinato-N,C（2）） picolinate.The emtting layer consists of poly（N-vinylcarbzole） （PVK） as host polymer,1,3-bis[（4-tert-butylphenyl）-1,3,4-oxadiazoly]-phenylene （OXD-7） as electron-transporting materials,Firpic and [（npy）2Ir（c-phen）]PF6.The structure of the WPLED is indium-tin-oxide/poly（3,4-ethylenedioxythiophene） doped with poly（styrenesulfonate）（40 nm）/emtting layer （80 nm）/CsF（1.5 nm）/Al（120 nm）.When the mass ratio of PVK,OXD-7,Firpic,[（npy）2Ir（c-phen）]PF6 is 67∶23∶10∶0.25,the most efficient white light is obtained with a color coordinate of （0.31,0.40）,a maximal luminance efficiency of 13.3 cd/A and a maximal luminance of 6032 cd/m2.Meanwhile,the color coordinate is unchanged with current density.The mechanism of the WPLED is discussed.%研究了掺杂离子型铱配合物的单发光层聚合物白光器件.根据二元互补色获得白光的原理,所采用离子型橙光材料为六氟磷酸合[二（2-（萘基-1-基）吡啶）（1-乙基-2-（9-（2-乙基己基）-9H-咔唑-3-基）-1H-咪唑并[4,5-f][1,10]菲啰啉）铱（Ⅲ）]（[（npy）2Ir（c-phen）]PF6）,天蓝光材料为二（2-（4,6-二氟苯基）吡啶-N,C（2））吡啶甲酰合铱（Firpic）.器件结构为氧化铟锡/苯磺酸掺杂聚乙烯基二氧噻吩（40nm）/发光层（80nm）/CsF（1.5nm）/Al（1
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