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Nanogap device: Fabrication and applications.

机译:纳米间隙器件:制造和应用。

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摘要

A nanogap device as a platform for nanoscale electronic devices is presented. Integrated nanostructures on the platform have been used to functionalize the nanogap for biosensor and molecular electronics. Nanogap devices have great potential as a tool for investigating physical phenomena at the nanoscale in nanotechnology. In this dissertation, a laterally self-aligned nanogap device is presented and its feasibility is demonstrated with a nano ZnO dot light emitting diode (LED) and the growth of a metallic sharp tip forming a subnanometer gap suitable for single molecule attachment.;For realizing a nanoscale device, a resolution of patterning is critical, and many studies have been performed to overcome this limitation. The creation of a sub nanoscale device is still a challenge. To surmount the challenge, novel processes including double layer etch mask and crystallographic axis alignment have been developed. The processes provide an effective way for making a suspended nanogap device consisting of two self-aligned sharp tips with conventional lithography and 3-D micromachining using anisotropic wet chemical Si etching. As conventional lithography is employed, the nanogap device is fabricated in a wafer scale and the processes assure the productivity and the repeatability. The anisotropic Si etching determines a final size of the nanogap, which is independent of the critical dimension of the lithography used.;A nanoscale light emitting device is investigated. A nano ZnO dot is directly integrated on a silicon nanogap device by Zn thermal oxidation followed by Ni and Zn blanket evaporation instead of complex and time consuming processes for integrating nanostructure. The electrical properties of the fabricated LED device are analyzed for its current-voltage characteristic and metal-semiconductor-metal model. Furthermore, the electroluminescence spectrum of the emitted light is measured with a monochromator implemented with a CCD camera to understand the optical properties. The atomically sharp metallic tips are grown by metal ion migration induced by high electric field across a nanogap. To investigate the growth mechanism, in-situ TEM is conducted and the growing is monitored. The grown dendrite nanostructures show less than 1nm curvature of radius. These nanostructures may be compatible for studying the electrical properties of single molecule.
机译:提出了一种纳米间隙器件作为用于纳米级电子器件的平台。平台上的集成纳米结构已用于功能化用于生物传感器和分子电子学的纳米间隙。纳米间隙器件作为研究纳米技术中的物理现象的工具具有巨大的潜力。本文提出了一种横向自对准的纳米间隙器件,并用纳米ZnO点发光二极管(LED)和金属尖锐尖端的生长形成了适合于单分子附着的亚纳米间隙,证明了其可行性。在纳米级器件中,图案的分辨率至关重要,并且已经进行了许多研究来克服这一限制。亚纳米级器件的创建仍然是一个挑战。为了克服挑战,已经开发了包括双层蚀刻掩模和结晶轴对准的新颖工艺。该方法提供了一种有效的方法来制造悬浮纳米间隙器件,该器件由两个具有自动光刻技术的自对准尖锐尖端组成,并使用各向异性湿化学Si蚀刻进行3-D微加工。由于采用了传统的光刻技术,纳米间隙器件以晶圆级制造,并且工艺确保了生产率和可重复性。各向异性的硅蚀刻确定了纳米间隙的最终尺寸,该尺寸与所使用光刻的临界尺寸无关。研究了一种纳米级发光器件。纳米ZnO点通过Zn热氧化,随后进行Ni和Zn覆盖蒸发而直接集成在硅纳米间隙器件上,而不是用于集成纳米结构的复杂且耗时的过程。分析了所制造的LED器件的电性能,以了解其电流-电压特性以及金属-半导体-金属模型。此外,用由CCD相机实现的单色仪测量发射的光的电致发光光谱以了解光学性质。原子尖锐的金属尖端是由高电场穿过纳米间隙引起的金属离子迁移而生长的。为了研究生长机理,进行了原位TEM并监测了生长。生长的树枝状纳米结构显示出小于1nm的半径曲率。这些纳米结构可以兼容用于研究单分子的电学性质。

著录项

  • 作者

    Han, Jun Hyun.;

  • 作者单位

    Marquette University.;

  • 授予单位 Marquette University.;
  • 学科 Engineering Electronics and Electrical.;Nanotechnology.;Engineering Mechanical.
  • 学位 Ph.D.
  • 年度 2014
  • 页码 150 p.
  • 总页数 150
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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