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Effects of frother type on single bubble rise velocity.

机译:起泡类型对单个气泡上升速度的影响。

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摘要

The addition of frother in flotation has two main functions, to help reduce bubble size and help produce a stable froth. A role of frother on bubble behavior in pulp zone is usually not considered. A previous study showed that as frother type was changed the same gas holdup was given by different size bubbles. This implies that bubble rise velocity depends on the nature of the surfactant (frother type). A study using bubble swarms appears to support the frother type effect but bubble interactions are a possible confounding factor.;To investigate, experiments were performed using aliphatic alcohols from 1-butanol (C4) to 1-octanol (C8). It was found there is a minimum concentration for the frother to give terminal velocity close to the Clift et al. contaminated eater result. The concentration decreases as molecular weight (chain length) of alcohol increases. Larger bubbles (1.8 vs. 1.5mm) require higher minimum concentration.;To study the influence of molecular structure, three 6-C alcohols, 1-hexanol, MIBC and 2-hexanol, were used. The results show that molecular structure influences rise velocity through the position of OH group, and whether the alcohol is straight chained or branched. The observation can make a useful link frother to chemistry for understanding frother influence on bubble rise and possibly its function in flotation.;The influence of three industrial frother, MIBC, F150 and DF250, was studied and it was observed that over the practical concentration range all reduce rise velocity similar to contaminated water and their critical concentration are very low compared to the aliphatic alcohols. In addition, the influence of a salt, NaCl, on bubble rise velocity was compared to MIBC and confirms a previous observation that reported the similar capability of NaCl to act like MIBC.;This study resolved the question by measuring terminal rise velocity profile of single bubbles (ca. 1 to 2 mm) as a function of frother type. It is shown that at the concentrations of interest in flotation, 1-pentanol hardly alters the velocity compared to water alone while F150 (a polyglycol) reduces the velocity by up to 50%. The results become in 1-pentanol bubble did not reach terminal velocity. For high concentration of 1-pentanol (>130ppm) the rise velocity is reduced comparable to F150.
机译:在浮选过程中添加起泡剂有两个主要功能,可帮助减小气泡尺寸并帮助产生稳定的泡沫。通常不考虑起泡剂对纸浆区域中气泡行为的作用。先前的研究表明,随着起泡剂类型的改变,不同大小的气泡会产生相同的气体滞留率。这意味着气泡上升速度取决于表面活性剂的性质(发泡剂类型)。使用气泡群的研究似乎支持起泡型效应,但气泡相互作用是可能的混杂因素。为了进行研究,使用1-丁醇(C4)至1-辛醇(C8)的脂族醇进行了实验。发现起泡剂的最小浓度可以使终速接近Clift等。食者受污染的结果。浓度随着醇的分子量(链长)的增加而降低。较大的气泡(1.8对1.5mm)需要较高的最小浓度。;为了研究分子结构的影响,使用了三种6-C醇,1-己醇,MIBC和2-己醇。结果表明,分子结构通过OH基团的位置以及醇是直链的还是支链的来影响上升速度。该观察结果可以为起泡剂与化学的联系提供有用的信息,以了解起泡剂对气泡上升及其在浮选中的作用的影响。所有这些都降低了上升速度,类似于被污染的水,与脂族醇相比,它们的临界浓度非常低。此外,将盐NaCl对气泡上升速度的影响与MIBC进行了比较,并证实了先前的报道,该观察报道了NaCl具有类似于MIBC的作用。泡沫类型(约1至2毫米)的函数。结果表明,在浮选中所关注的浓度下,与单独的水相比,1-戊醇几乎不会改变速度,而F150(一种聚乙二醇)最多可将速度降低50%。结果变成1-戊醇气泡未达到最终速度。对于高浓度的1-戊醇(> 130ppm),上升速度的降低幅度与F150相当。

著录项

  • 作者单位

    McGill University (Canada).;

  • 授予单位 McGill University (Canada).;
  • 学科 Engineering Metallurgy.
  • 学位 M.Eng.
  • 年度 2009
  • 页码 123 p.
  • 总页数 123
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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