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Directional solidification of indium antimonide under high gravity in large centrifuges.

机译:大型离心机在高重力下锑化铟的定向凝固。

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Thirteen ingots of undoped InSb, Te-doped InSb and Se-doped InSb were directionally solidified in a gradient freeze furnace mounted at the end of the 18 m arm of a centrifuge in the USSR. Each ingot was subjected to a different acceleration level during growth. One Se-doped InSb ingot was solidified in a centrifuge in France with an arm length of 5.5 m. An undoped InSb ingot grown at 9 g (g = 9.81 m/s{dollar}sp2{dollar}) consisted primarily of a single grain containing a number of twins. The microstructure of the ingots depended on the acceleration and on the doping. Te-doped InSb grown at 9 g had the fewest grain and twin boundaries, while Se-doped InSb grown at 9 g had the most grain boundaries. For undoped ingots, InSb grown at 7 g had the fewest twin boundaries. Reproducibility experiments on grain and twin boundary counts showed that differences in microstructure seen in the ingots solidified in the centrifuges were statistically significant. No dopant striations were observed in any of the ingots, indicating that the freezing rate did not fluctuate. With doping, microcracks sometimes occurred, but never without doping. Centrifuge processing almost completely eliminated the bubbles normally present on the outer surface of InSb ingots. Undoped InSb ingots were either n or p-type, while Te and Se-doped ingots were n-type. The axial hole concentration in undoped InSb grown at 9 g was constant. Polycrystallinity of the InSb ingots caused a lot of scatter in resistivity and mobility data.; HIRB (High Inertia Rotating Behemoth) is a novel modification of a variable speed, 62 inch King boring mill. The arm radius for experiments is 1.524 m. The maximum rotation rate attainable is 90 rpm, which corresponds to a maximum acceleration of {dollar}approx{dollar}15 g. The centrifuge was instrumented with equipment for performing crystal growth experiments at high gravity.; Ten ingots of Te-doped InSb were directionally solidified in a gradient freeze furnace mounted at the end of the arm of HIRB at various acceleration levels. All ingots were polycrystalline. Ingots grown at 2 g had the fewest grains compared to the ingots grown at other acceleration levels. Growth of InSb at high acceleration reduced the bubbles present on the outer surface of the ingots. No distinct trend in the resistivity with acceleration was observed in either the axial or radial directions. Ten ingots of doped InSb were grown to try to produce interface demarcations by using incremental quenching, complete quenching and melt-back and regrowth techniques. No striations were obtained. Furnace power consumption decreased from 1 g to 2 g. Between 2 g and 8 g the furnace power consumption was almost constant. Acceleration and vibration analysis on HIRB revealed a 17 Hz low frequency vibration component in the direction of rotation of the centrifuge. (Abstract shortened by UMI.)
机译:在安装在苏联18 m离心机臂末端的梯度冷冻炉中,定向凝固了13个未掺杂的InSb,Te掺杂的InSb和Se掺杂的InSb锭。每个锭在生长过程中都受到不同的加速水平。在法国的离心机中,将一根硒掺杂的InSb锭固化,臂长为5.5 m。以9 g(g = 9.81 m / s {dol}} sp2 {dollar}生长的未掺杂InSb锭主要由包含多个孪晶的单个晶粒组成。铸锭的微观结构取决于加速度和掺杂。以9 g生长的Te掺杂的InSb具有最少的晶粒和孪晶边界,而以9 g生长的Se掺杂的InSb具有最大的晶粒边界。对于未掺杂的晶锭,以7 g生长的InSb的孪晶边界最少。晶粒和孪晶边界计数的可重复性实验表明,在离心机中凝固的铸锭中观察到的微观结构差异具有统计学意义。在任何铸锭中均未观察到掺杂剂条纹,表明冻结速率没有波动。掺杂时,有时会发生微裂纹,但从来没有掺杂过。离心处理几乎完全消除了通常存在于InSb铸锭外表面的气泡。未掺杂的InSb锭为n型或p型,而Te和Se掺杂的锭为n型。以9 g生长的未掺杂InSb中的轴向孔浓度是恒定的。 InSb铸锭的多晶性导致电阻率和迁移率数据发生大量分散。 HIRB(高惯性旋转庞然大物)是对62英寸变速王镗铣床的一种新颖修改。实验的手臂半径为1.524 m。可达到的最大转速为90 rpm,相当于最大加速度约为15 g。离心机装有用于在高重力下进行晶体生长实验的设备。在安装在HIRB臂末端的梯度冷冻炉中,以不同的加速度水平定向凝固10个掺Te的InSb锭。所有的锭都是多晶的。与以其他加速度水平生长的锭相比,以2 g生长的锭的晶粒最少。 InSb在高加速度下的生长减少了铸锭外表面上存在的气泡。在轴向或径向上均未观察到电阻率随加速度的变化趋势。生长十个掺杂的InSb锭,以尝试通过使用增量淬火,完全淬火以及回熔和再生技术来产生界面分界。没有获得条纹。熔炉功耗从1 g降低到2 g。在2 g和8 g之间,炉子的功率消耗几乎是恒定的。在HIRB上进行的加速和振动分析显示,在离心机旋转方向上存在17 Hz的低频振动分量。 (摘要由UMI缩短。)

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