首页> 外文学位 >Modeling and optimization of a two-stage regenerator fluid catalytic cracking unit.
【24h】

Modeling and optimization of a two-stage regenerator fluid catalytic cracking unit.

机译:两级蓄热式流化床催化裂化装置的建模和优化。

获取原文
获取原文并翻译 | 示例

摘要

In Petroleum refining, the Fluid Catalytic Cracking Unit (FCCU) is the critical stage in the processing of heavy hydrocarbon oils into more valuable gasoline and lighter products. In the FCCU process, the catalyst becomes deactivated in the reactor by heavy carbon deposits called coke. Catalyst activity is restored in the regenerator by burning off the coke with air. Steam formation during high temperature single-stage regeneration can cause permanent catalyst deactivation. Two stage regeneration allows steam formation to occur in the lower temperature first stage minimizing permanent catalyst deactivation. Heavier feedstocks have led to increased usage of two-stage regeneration.; A new FCC model has been developed for modeling a unit that has a two-stage regenerator. The model incorporates the ten lump kinetic model of Jacob et al. for the riser and a three phase model based on the work of Gwyn et al. for the dense bed of the regenerator. The overall model, consisting of ODEs, is solved with a sequential modular algorithm.; Simulation results using the model are consistent with real operating conditions. The riser spatial results show most of the reactions to occur in the first 20% of the length of the riser. The dense bed spatial results are similar to expected fluidized bed operations in that most of the bed is uniform in temperature and concentration with a small section where gradients occur.; Optimization studies have determined that for maximizing gasoline yield, defined here as pounds gasoline per pound feed, lower feed rates are favored and selectivity is important. For maximizing total gasoline production, feed throughput becomes the important factor at the expense of selectivity. An economic study is included showing optimal conditions for a range in crack spread.
机译:在石油精炼中,流化催化裂化装置(FCCU)是将重质烃油加工成更有价值的汽油和更轻质产品的关键阶段。在FCCU工艺中,催化剂在反应器中被称为焦炭的重碳沉积物钝化。通过用空气燃烧焦炭,可在再生器中恢复催化剂活性。高温单级再生过程中形成的蒸汽会导致催化剂永久失活。两阶段再生允许在较低温度的第一阶段发生蒸汽形成,从而最大程度地减少永久性催化剂失活。较重的原料导致两阶段再生的使用增加。已开发出新的FCC模型来对具有两级再生器的单元进行建模。该模型结合了Jacob等人的十块动力学模型。立管和基于Gwyn等人工作的三相模型。用于再生器的致密床。用顺序模块化算法求解由ODE组成的整体模型。使用该模型的仿真结果与实际操作条件一致。立管空间结果显示,大多数反应发生在立管长度的前20%。致密床的空间结果与预期的流化床操作相似,因为大多数床的温度和浓度是均匀的,并且有小部分出现梯度。优化研究已经确定,为了使汽油产量最大化(此处定义为每磅进料的汽油磅数),较低的进料速率是有利的,并且选择性很重要。为了使汽油总产量最大化,进料量成为重要的因素,而牺牲了选择性。包括的经济研究表明,裂纹扩展范围的最佳条件。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号