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Condensational Droplet Growth in Rarefied Quiescent Vapor and Forced Convective Conditions.

机译:稀有静态蒸气和强制对流条件下的冷凝液滴生长。

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摘要

Multiphase Heat transfer is ubiquitous in diverse fields of application such as cooling systems, micro and mini power systems and many chemical processes. By now, single phase dynamics are mostly understood in their applications in vast fields, however multiphase systems especially involving phase changes are still a challenge.;Present study aims to enhance understanding in this domain especially in the field of condensation heat transfer. Of special relevance to present studies is study of condensation phenomenon for detection of airborne nanoparticles using heterogeneous nucleation. Detection of particulate matter in the environment via heterogeneous condensation is based on the droplet growth phenomenon where seeding particles in presence of supersaturated vapor undergo condensation on their surface and amplify in size to micrometric ranges, thereby making them optically visible. Previous investigations show that condensation is a molecular exchange process affected by mean free path of vapor molecules (lambda) in conjunction with size of condensing droplet (d), which is measured in terms of Knudsen number (Kn=lambda/ d). In an event involving heterogeneous nucleation with favorable thermodynamic conditions for condensation to take place, the droplet growth process begins with accretion of vapor molecules on a surface through random molecular collision (Kn>1) until diffusive forces start dominating the mass transport process (Kn1). Knowledge of droplet growth thus requires understanding of mass transport in both of these regimes.;Present study aims to understand the dynamics of the Microthermofluidic sensor which has been developed, based on above mentioned fundamentals. Using continuum approach, numerical modeling was carried to understand the effect of various system parameters for improving the device performance to produce conditions which can lead to conditions abetting condensational growth. The study reveals that the minimum size of nanoparticle which can be detected is critically dependent upon controlling wall geometry and size, wall temperature, flow rate and relative humidity of nanoparticle laden air stream. Droplet growths rates and sizes have been predicted based on different models. The efficacy of the device under various conditions has been measured in terms of its ability to activate nanoparticles of different sizes.;Since the condensation mechanism is dependent upon the Knudsen regime in which droplets are growing via condensation, special consideration was made to understand their behavior in large Knudsen number conditions. For this purpose, ESEM was used to study condensation on a bare surface. Droplet growth obtained as a function of time reveals that the rate of growth decreases as the droplet increases in size. The experimental results obtained from these experiments were matched with theoretical description provided by a model based on framework of kinetic theory. Evidence was also found which establishes the presence of submicroscopic droplets nucleating and growing in between microscopic droplets for partially wetting case.
机译:多相传热在各种应用领域中无处不在,例如冷却系统,微型和小型动力系统以及许多化学过程。到目前为止,单相动力学在广阔领域中的应用已广为人知,然而,尤其是涉及相变的多相系统仍是一个挑战。本研究旨在加强对这一领域的理解,尤其是在冷凝传热领域。与本研究特别相关的是利用异相成核法检测空气中纳米颗粒的凝结现象。通过异质冷凝来检测环境中的颗粒物是基于液滴生长现象,在这种现象中,存在过饱和蒸汽的晶种颗粒在其表面上发生冷凝,并在尺寸上扩大到微米范围,从而使它们在光学上可见。先前的研究表明,冷凝是一种分子交换过程,受蒸汽分子(λ)的平均自由程以及冷凝液滴(d)的大小影响,冷凝液滴的大小以克努森数(Kn = lambda / d)表示。在涉及具有良好热力学条件以进行冷凝的非均相成核的情况下,液滴的生长过程始于通过随机分子碰撞(Kn> 1)在表面上积聚蒸汽分子,直到扩散力开始主导质量传输过程(Kn < <1)。因此,要了解液滴的生长,就需要了解这两种情况下的质量传输。;本研究旨在了解基于上述基本原理而开发的微热流体传感器的动力学特性。使用连续方法,进行了数值建模,以了解各种系统参数对改善器件性能产生条件的影响,这些条件可能导致条件促使凝结生长。研究表明,可以检测到的纳米颗粒的最小尺寸关键取决于控制壁的几何形状和尺寸,壁温,流速和载有纳米颗粒的空气流的相对湿度。液滴的生长速率和大小已根据不同的模型进行了预测。已根据其激活不同尺寸纳米颗粒的能力来测量该设备在各种条件下的功效。;由于冷凝机制取决于液滴通过冷凝生长的克努森制度,因此需要特别考虑以了解其行为在大努森数条件下。为此,ESEM用于研究裸露表面上的冷凝。作为时间的函数而获得的液滴生长表明,随着液滴尺寸的增加,增长率会降低。从这些实验获得的实验结果与基于动力学理论框架的模型提供的理论描述相匹配。还发现证据表明,对于部分润湿的情况,亚微观液滴在微观液滴之间成核并生长。

著录项

  • 作者

    Anand, Sushant.;

  • 作者单位

    University of Cincinnati.;

  • 授予单位 University of Cincinnati.;
  • 学科 Nanoscience.;Physics Fluid and Plasma.
  • 学位 Ph.D.
  • 年度 2011
  • 页码 150 p.
  • 总页数 150
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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