Optical Sensing and Trapping Based on Localized Surface Plasmons.

摘要

This project involves the study of novel plasmonic nanodevices that provide unique functionality in optical sensing, surface-enhanced Raman scattering (SERS), and optical trapping.;The first design is based on a coupling system involving double-layered metal nano-strips arrays. This system has the advantages of simple geometry and direct integration with microfluidic chips. The intense optical localization due to field coupling within the system can enhance detection sensitivity of target molecules, especially by virtue of the optical trapping of plasmonic nanoparticles. The optical resonant condition is obtained theoretically through analyzing the SPs modes. Numerical modeling based on two-dimensional (2D) finite-difference time-domain (FDTD) is consistent with the theoretical analysis and demonstrates the feasibility of using this system for optical sensing and trapping.;In the second design, a gold nano-ring structure is demonstrated to be an effective approach for plasmonic nano-optical tweezers (PNOTs) for trapping metallic nanoparticles. In our demonstration example, we have optimized a device for SERS operation at the wavelength of 785 nm. Three-dimensional (3D) FDTD techniques have been employed to calculate the optical response, and the optical force distribution have been derived using the Maxwell stress tensor (MST) method. Simulation results indicate that the nano-ring produces a maximum trapping potential well of ~32 kBT on a 20 nm gold nanoparticle. The existence of multiple potential well results in a very large active trapping volume of ~106 nm3 for the target particles. Furthermore, the trapped gold nanoparticles further lead to the formation of nano-gaps that offer a near-field enhancement of ~160 times, resulting in an achievable EF of 108 for SERS.;In the third design, we propose a concept of all-optical nano-manipulation. We show that target molecules, after being trapped, can be transferred between the trapping sites within a linear array of PNOTs. The system consists of an array of graded plasmonic nano-disks (NDs) with individual elements coded with different resonant wavelengths according to their dimensions. Thus, by switching the wavelength and rotating the polarization of the excitation source, the target nanoparticles trapped by the device can be manipulated from one ND to another. 3D FDTD simulation and MST calculation are utilized to demonstrate the operation of this idea. Our results reveal that the target experiences a trapping potential strength as high as 5000 kBT/W/microm 2, maximum optical torque of ~336 pN˙nm/W/microm2, and the total active volume may reach ~106 nm3. The potential applications in terms of optical sensing are also discussed.;In the final design, for which experimental demonstration has been conducted, we show that PNOTs are achievable with random plasmonic nano-islands. Two laser beams having wavelengths of 633 nm and 785 nm are utilized to stimulate the PNOTs and excite the Raman signals simultaneously. The PNOTs are formed by annealing of a thermal evaporated gold film. This so-called nano-island substrate (Au-NIS) has a resonant peak close to 633 nm. The target is photochemical synthesized silver nanodecadedrons (AgNDs) functionalized with 4-Mercaptobenzoic acid (4-MBA) and the resonant peak of these AgNDs is far away from 633 nm and 785 nm. As the target is trapped to the hot-spots when the PNOTs are active, the near-field intensity is enhanced significantly, which results in the emergence of SERS signals, i.e. confirming the expected outcome of SERS upon nanotrapping by the PNOTs. This process is also elucidated numerically through 3D FDTD simulation and MST calculation. Furthermore, the target can be released as the PNOTs become inactive, i.e. disappearance of the SERS signal. Therefore, this design offers not only a robust avenue for monitoring trapping events in PNOTs, but also a reproducible "trap-and-sense" platform for bio-detection. (Abstract shortened by UMI.).