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含离子液体多组分体系汽液相平衡的测定和关联

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英文文摘

北京化工大学学位论文原创性声明

Chapter 1 General summary and selected thesis

1.1 Introduction to separation processes

1.1.1 The nature of equilibrium

1.1.2 Azeotropic systems

1.1.3 Determination of azeotrope

1. 2 Extractivedistillation

1.2.1 Extractive mechanism

1.2.2 Selecting the extractant (agent)

1.3 Correlations and predictions of VLE

1.3.1 Antoineequation

1.3.2 NRTL equation

1.4 Summaryof main work

Chapter2 Vapor spressure Measurement for Multi-component Mixtures ContainingILs [PMIM]Br using a modified boiling point method

2.1 Introduction

2.2 Experiment materials

2.3 Experiment apparatus

2.4 Experiment procedures

2.4.1 Vapor pressure measurement of pure component

2.4.2 Vapor pressure measurement of binary and ternary systems

2.5 Results and discussions

2.6 Conclusion

Chapter 3 Vapor Pressure Measurement and Correlation for Binary Mixtures of Water, Ethanol and Benzene with [BMIM]Br, [BMIM]CI and [BMIM]-bibutylphosphate

3.1 Introduction

3.2 Experiment materials

3.3 Experiment apparatus

3.4 Experimental Procedures

3.4.1 Vapor Pressure Measurements of Pure Components

3.4.2 Vapor pressure measurement of binary systems

3.5 Results and Discussion

3.6 Conclusion

Chapter 4 Effectof ionic liquidson the VLE of benzene-ethanol system at 101.3 kPa

4.1 Introduction

4.2 Experiment materials

4.3 Experiment apparatus

4.4 Experiment procedures

4.4.1 VLE for benzene-ethanol binary system

4.4.2 VLE measurement for the ternary systems

4. 5 Results and discussions

4.5.1 VLE on separating benzene and ethanol by extractive distillation

4.6 Conclusion

NOMENCLATURE

References

Acknowledgment

Published papers

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摘要

本文通过实验研究离子液体对汽液相平衡产生的盐效应,对在萃取精馏过程中使用了离子液体作为一种中绿色萃取剂的可能性进行了探索。文章在三元混合物水—乙醇—溴化1—丙基—3—甲基咪唑的不同温度离子液体不同含量的情况下,使用修正沸点法测定了的体系的气压。实验结果用Antoine方程进行关联,关联结果良好。实验结果说明,由于离子液体与溶剂之间的亲和力溶剂的蒸气压显著的降低,亲和力不同,蒸气压降低程度不同,这于普通无机盐的盐效应相似。研究结果表明:离子液体在工业上可用于分离因子较低的体系及共沸体系的萃取精馏。研究离子液体在萃取精馏过程中的应用是具有一定前景的。

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