声明
1. Introduction
1.1. The CO2 question
1.2. Combustion
1.2.1. Oxy-fuel combustion
1.2.2. Pre-combustion
1.2.3 Post-combustion
1.3. Adsorption
1.3.1. Chemisorption
1.3.2. Physisorption
1.3.3. Swing adsorption
1.4.Economically important point
1.4.1. Cost of adsorbent
1.4.2. CO2 and cyclic capacity
1.4.3. Selectivity
1.5. Existing adsorbents
1.5.1. Activated Carbon
1.5.2. Zeolites
1.5.3. Metal Organic Framework
1.5.4. Zeolitic Imidazolate Framework
1.6. Synthetization
1.6.1. Synthetization of ZIFs
1.6.2. Solvent Based Synthetization method
1.6.3. Solvent free synthetization
2. Experiment
2.1. Synthesize ZIF-67
2.1.1.Synthesize ZIF-67 from sulfate source
2.1.2.Synthesize ZIF-67 with DMF
2.2. Reaction condition
2.2.1. Stirring time
2.2.2. Centrifuge
2.2.3. The amount of the 2-methylimidazolate
2.2.4. The amount of the Copper
2.2.5. The amount of the Deionized water
2.2.6. Compare of the Hydrothermal and Solvothermal synthesis
2.2.7. Storage of the samples
2.3. The breakthrough experiment
2.3.1. The secondary product
2.4. XRD pictures
2.5.Thermogravimetric Analysis
2.6. Scanning Electron Microscope
2.7. Adsorption tests
3. Conclusion
参考文献
