Effects of Hydrogen-Enriched Reduction on Metallurgical Properties of Iron-Bearing Burdens Under BF Operation with COG Injection

摘要

Coke oven gas (COG) injection is considered as one of feasible measures to reduce carbon emission of BF. The effects of COG injection on the reduction of iron-bearing burdens were numerically simulated by means of multi-fluid BF model, which revealed that with increasing COG injection rate, solid temperature gradually decrease, in-furnace H_2 concentration increases, the reduction of magnetite and wustite by H_2 is evidently accelerated, the reaction rate of wustite by H_2 reduction is enhanced and the reduction degree of mixed burdens is strengthened. Under this hydrogen-enriched condition, metallurgical properties of iron-bearing burdens were experimentally investigated. The GB/T13242-91 test results showed that with increasing COG injection rate, the reduction swelling index of oxidized pellets decreases while the reduction ratio of pellets increases. The softening-melting tests suggested that softening interval of mixed burdens increases from 163.6 to 228.3 ℃ while melting interval decreases from 147.3 to 92.4 ℃. The cohesive zone moves downwards and becomes narrow. The permeability of mixed burdens is improved. In terms of metallurgical properties of iron-bearing burdens, COG injection benefits to improve BF performance.