EFFECT OF ADDITIONAL MAO ON DIENE POLYMERIZATION INITIATED WITH ACTIVE Nd-Al BIMETALLIC SPECIES

机译：活化反应对活性Nd-Al双金属物种引发的二烯聚合反应的影响

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Based on the isolation of a polynuciear Nd-Al bimetallic complex, which alone can initiate diene polymerization without the presence of co-catalyst, the effects of addition of MAO ( methyl aluminoxane ) on diene polymerization were studied in detail, furthermore, and the comparision between the results of MAO and some aluminum trialkyls was also made.

机译：在分离多核Nd-Al双金属配合物的基础上，该双核Nd-Al双金属配合物仅能在不存在助催化剂的情况下引发二烯聚合，此外，还详细研究了添加MAO（甲基铝氧烷）对二烯聚合的影响，并进行了比较在MAO的结果和一些三烷基铝之间也进行了分析。

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来源
《The 2nd China-Italy joint polymer symposium》|1995年|25-26|共2页
会议地点 Hangzhou(CN)
作者
Dong Weimin; Shan ChengJi; Yang Jihua; Huang Baotong;
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作者单位

Changchun Institute of Applied Chemistry, Academia Sinica;

Changchun Institute of Applied Chemistry, Academia Sinica;

Changchun Institute of Applied Chemistry, Academia Sinica;

Changchun Institute of Applied Chemistry, Academia Sinica;

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会议组织
原文格式 PDF
正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
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机译：齐格勒-纳塔型催化剂存在下共轭二烯的聚合机理：CpTiCl3-MAO引发剂丁二烯和异戊二烯聚合反应的理论研究[综述]
2. Synthesis and X-ray Structure of CoCl_2(P~iPrPh_2)_2.A New Highly Active and Stereospecific Catalyst for 1,2 Polymerization of Conjugated Dienes When Used in Association with MAO [J] . Giovanni Ricci, Alessandra Forni, Aldo Boglia Macromolecules . 2005,第4期

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3. Diethylbis(2,2 '-bipyridine)iron/MAO. A very active and stereospecific catalyst for 1,3-diene polymerization [J] . Bazzini C., Giarrusso A., Porri L. Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation . 2002,第15期

机译：二乙基双（2,2'-联吡啶）铁/ MAO。一种非常活跃的立体定向催化剂，用于1,3-二烯聚合
4. EFFECT OF ADDITIONAL MAO ON DIENE POLYMERIZATION INITIATED WITH ACTIVE Nd-Al BIMETALLIC SPECIES [C] . China-Italy joint polymer symposium . 1995

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EFFECT OF ADDITIONAL MAO ON DIENE POLYMERIZATION INITIATED WITH ACTIVE Nd-Al BIMETALLIC SPECIES

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