MANUFACTURE OF INTEGRAL SKIN PP FOAM COMPOSITES IN ROTATIONAL MOLDING

摘要

The feasibility of applying the single-charge rotational foam molding processing principle to the fabrication of integral skin polypropylene (PP) foams comprising a PP solid skin and a PP foamed core is investigated in this paper. A systematic process interruption and sample evaluation approach was used to quantify the experimental results and explore possibilities for improving the process control strategies to ultimately achieve a desired homogeneity and thickness uniformity of the solid PP skin layer that would be fully encapsulating the PP foamed core of a desired cell population density and average cell size. The experimental results revealed that this is quite a challenging task not only because of the well known intrinsically poor foaming nature of PP due to its low melt strength at elevated temperatures, but also because in single-charge rotational molding the processing parameters are often conflicting each other and therefore have to be optimized within a very narrow processing window. However, simultaneous, single-charge, quality PP integral skin and foamed PP core formation in rotational foam molding is feasible. Optimizing the heating profile, heating rate, heating time, and the mold rotational speed as well as careful selection of PP resins (or resin blends), chemical blowing agents (CBA), and their composition formulations is strongly recommended.