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A Pulse Radiolysis Study of Oil/Water Microemulsions

机译:油/水微乳的脉冲辐射分解研究

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摘要

The spectrum and yield of e_aq~- in quaternary benzene/water and dodecane/water microemulsions were found to be identical with those in pure water. This indicates probably the scavenging of excess electrons produced in the oil by water. To the contrary, the yield of OH radicals, determined after scavenging and conversion into (SCN)2~-, was proportional to water content of the microemulsion. the e_aq~- decay and the total yield of peroxides in aerated microemulsion were determined and the characteristics of oxidation in microemulsion was discussed.
机译:在季苯/水和十二烷/水微乳液中,e_aq〜-的光谱和产率与纯水中的相同。这可能表明水清除了油中产生的过量电子。相反,在清除并转化为(SCN)2-后确定的OH自由基的产率与微乳液的水含量成比例。测定了充气微乳中的e_aq〜-衰减和过氧化物的总收率,并讨论了微乳中的氧化特性。

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