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Synthesis and Characterization of YAG:Ce~(3+)Nanophosphor Prepared by Flame Spray Pyrolysis

机译:火焰喷雾热解法制备的YAG:Ce〜(3+)纳米磷光体的合成与表征

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摘要

Among the various types of synthesis techniques for phosphors, flame spray pyrolysis (FSP) is a powerful method which is capable of producing particles with good crystallinity and high luminescence efficiency. In this work, we have studied the possibility of producing yellow light emitting Ce~(3+) doped Y_3Al_5O_(12) (YAG:Ce~(3+)) nanophosphor particles using FSP. The challenges in forming YAG arise because of its complex stoichiometry and existence of numerous crystalline states. 3 M of urea was added to increase the flame temperature. The as-prepared nanoparticles were annealed in the temperature range 800℃ to 1100℃ for 1 hour. As-prepared phosphor particles were found to be YAlO_3 which transformed to YAG when annealed above 900 ℃ . PL intensity of the phosphors increased with increase in annealing temperature. These results indicate the possibility of fabrication of high quality YAG:Ce~(3+) nanophosphor particles via a simple process.
机译:在各种类型的荧光粉合成技术中,火焰喷雾热解(FSP)是一种功能强大的方法,能够生产出具有良好结晶度和高发光效率的颗粒。在这项工作中,我们研究了使用FSP生产黄色发光Ce_(3+)掺杂Y_3Al_5O_(12)(YAG:Ce〜(3+))纳米磷光体颗粒的可能性。形成YAG的挑战是由于其复杂的化学计量比和许多晶态的存在。加入3M尿素以提高火焰温度。将所制备的纳米颗粒在800℃至1100℃的温度范围内退火1小时。制备的荧光粉颗粒为YAlO_3,在900℃以上退火时转变为YAG。磷光体的PL强度随着退火温度的升高而增加。这些结果表明可以通过简单的方法制备高质量的YAG:Ce〜(3+)纳米磷光体颗粒。

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  • 来源
  • 会议地点 Honolulu HI(US);Honolulu HI(US)
  • 作者单位

    Department of Materials Science Engineering, University of Florida, Gainesville, Florida 32611, USA;

    Department of Materials Science Engineering, University of Florida, Gainesville, Florida 32611, USA;

    Department of Materials Science Engineering, University of Florida, Gainesville, Florida 32611, USA;

    Particle Engineering Research Center, University of Florida, Gainesville, Florida 32611, USA;

    Department of Materials Science Engineering, University of Florida, Gainesville, Florida 32611, USA;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 电气照明;
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