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Enhancement of Electrocatalytic Activity of Octahedral Au@Pt Core-Shell Nanoparticles by the Surface Plasmon Excitation

机译:表面等离子激发增强八面体Au @ Pt核壳纳米粒子的电催化活性

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Octahedral Au-core Pt-shell (Au@Pt) nanoparticles were successfully prepared via a galvanic replacement of Cu monolayer underpotentially deposited on Au core with a Pt monolayer. The visible light irradiation to Au@Pt nanoparticles-immobilized electrodes enlarged a cathodic current of oxygen reduction reaction (ORR), suggesting that the electrocatalytic activity of Pt shell layer was enhanced by the photoexcitation of localized surface plasmon resonance peak of octahedral Au-core particles.
机译:八面体Au核Pt壳(Au @ Pt)纳米粒子是通过用电势置换用Pt单层欠电位沉积在Au核上的Cu单层成功制备的。固定在Au @ Pt纳米颗粒上的电极的可见光照射扩大了氧还原反应(ORR)的阴极电流,这表明光激发八面体Au核颗粒的局部表面等离子体激元共振峰增强了Pt壳层的电催化活性。 。

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