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机译:与CW设施相关的空气质量监测

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摘要

This presentation deals with possibility of using a deyice, based on the GC-IMS principle, for monitoring chemical warfare agents that are subject to the Chemical Weapons Convention. This device was tested if applicable to detect chemical warfare agents as well as agents of homologous alkylmethylfluorophosphonate series derived from methylfluorophosphonate. Up-to-date results obtained by testing are presented and basic parameters are analyzed. In order to consider usability of the discussed method, measurements of isopropylmethylfluorophosphonate (GB), pinacolylmethyl-fluorophosphonate (GD), n-propylmethylfluorophosphonate (PMFP), n-butylmethyl-fluorophosphonate (BMFP), n-pentylmethylfluorophosphonate (PeMFP), n-hexylmethylfluorophosphonate (HMFP) were carried out. For these mentioned compounds, basic chromatographic data and ionic mobility spectra are presented in this paper. Obtained data are evaluated with regard to their selectivity and ability to differentiate individual compounds of homologous series. The GC/IMS instrument designed for monitoring toxic agents presence in the workong atmosphere is also evaluated from the point of view of its global usage.
机译:本演示介绍了使用基于GC-IMS原理的设备监测受《化学武器公约》约束的化学战剂的可能性。测试该装置是否适用于检测化学战剂以及衍生自甲基氟膦酸酯的同源烷基甲基氟膦酸酯系列试剂。介绍了通过测试获得的最新结果,并分析了基本参数。为了考虑所讨论方法的可用性,测量了异丙基甲基氟代膦酸酯(GB),频哪醇甲基氟代膦酸酯(GD),正丙基甲基氟代膦酸酯(PMFP),正丁基甲基氟代膦酸酯(BMFP),正戊基甲基氟代膦酸酯(PeMFP),正己基甲基氟代膦酸酯(HMFP)进行。对于这些提到的化合物,本文提供了基本色谱数据和离子迁移谱。评估获得的数据的选择性和区分单个同源系列化合物的能力。还从其全球使用的角度评估了用于监控工作环境中有毒物质存在的GC / IMS仪器。

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