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Hot-Jet Ignition of Hydrocarbons and Hydrogen in Air: Effect of Jet Chemical Activity

机译:空气中碳氢化合物和氢气的热喷射点火:喷射化学活性的影响

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A jet of hot reactive gas can reliably ignite premixed gases in combustion engines. The presence of chemically active species in the hot jet may influence the time delay and ignitability limits for ignition of a combustible mixture. Rapid ignition and combustion may also involve complex interactions of pressure waves with flames in the transient jet, especially in a wave-rotor constant-volume combustor for gas turbine performance enhancement. In the present work, detailed numerical simulations are carried out to understand the relative role of chemical kinetics and turbulent mixing in a transient hot jet on ignition in a constant-volume combustor. A transient hot jet is modeled in two ways: as a relatively inert hot jet and as a radical-rich chemically active hot jet for slightly rich ethylene-air mixture. Combustion is modeled in the main constant-volume chamber for methane, hydrogen and blended methane-hydrogen mixtures. A hybrid eddy-break-up combustion model is applied, with detailed or reduced reaction mechanisms and the two-equation k-ω model. For stoichiometric methane mixture in the main chamber, the predicted ignition of the blended fuel mixture was surprisingly not any faster than that of pure methane. The ignition delay time of the more chemically active jet is slightly shorter than a jet of similar composition with only stable species. These observations generally point to a complex interaction of physical and chemical process in hot-jet ignition in a confined volume with shock dynamics and jet mixing processes playing a role that may be as important as chemical kinetics.
机译:热反应气射流可靠地点燃燃烧发动机中的预混合气体。热射流中的化学活性物质的存在可能影响用于点火可燃混合物的时间延迟和可燃性限制。快速点火和燃烧还可以涉及压力波与瞬态射流中的火焰的复杂相互作用,尤其是用于燃气轮机性能增强的波转子恒定体积燃烧器。在本作工作中,进行详细的数值模拟,以了解化学动力学和湍流混合在恒定体积燃烧器中点火上的瞬态热喷射中的相对作用。瞬态热射流以两种方式建模:作为相对惰性的热射流,作为富含富含乙烯 - 空气混合物的自由基化学活性热射流。燃烧在甲烷,氢和混合甲烷 - 氢气混合物中的主恒定室建模。应用混合涡流燃烧模型,具有详细或降低的反应机制和双等式K-Ω模型。对于主室中的化学计量甲烷混合物,混合燃料混合物的预测点火令人惊讶地没有比纯甲烷更快。更具化学活性射流的点火延迟时间略短于仅具有稳定物种的类似组合物的射流。这些观察结果通常指向具有震动动力学和喷射混合过程的狭窄体积中的热喷射点火中的物理和化学过程的复杂相互作用,其扮演可能与化学动力学一样重要的作用。

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