Cyclic and frame hydrocarbons. The energy of rearrangement of the radicals

摘要

On the basis of enthalpy of formation of cyclic and frame compounds and their radicals in the gas phase, the energies of radical reorganization are determined. For calculations used the thermochemical data for monocyclic compounds from cyclopropane to cyclododecane and adamantane, cuban and other substances and related radicals. In the calculations used previously identified pattens for mean thermochemical energies of the bonds of aliphatic compounds and energies of the reorganization of the radicals.