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Leaching Behaviors of Heavy Metals from Mortar in Various Types of Solutions

机译:各类解决方案中砂浆的重金属的浸出行为

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Reduction of municipal wastes is important,and one of the probable solutions is to utilize by-products and wastes such as blast furnace slag and incinerated ash in eco-concrete.However,municipal wastes may contain heavy metals,and it is well known that heavy metal ions can be easily adsorbed on cement hydrates.On the other hand,it is also found that adsorbed heavy metal ions can be easily leached in the presence of calcium chloride.In the present study,the leaching behavior of heavy metal ions from mortar specimens immersed in various types of solutions was investigated.The results show that the leaching amount of the lead ions from the specimens immersed in CaCl2 solution was three times as large as that in the other solutions.However,the difference in the pore volume of the specimens after immersion between types of solutions was not observed.Besides,it is also found that in the case of the specimen with a water cement materials ratio of 0.40,the pore structures of mortar specimens were relatively denser and the pH value of the solution was lower compared with the case of the specimen with a water cement materials ratio of 0.55.This can result in smaller leaching amounts of heavy metals.
机译:市政废物的减少是重要的,其中一个可能的解决方案是利用副产品和垃圾,如高炉炉渣和焚烧灰烬在生态混凝土中。然而,城市废物可能含有重金属,众所周知,重众所周知金属离子可以容易地吸附在水泥水合物上。另一方面,还发现吸附的重金属离子可以在氯化钙存在下容易地浸出。本研究中,重金属离子与砂浆样本的浸出行为研究了各种类型的溶液。结果表明,从CaCl 2溶液中浸入的样品中铅离子的浸出量为另一个溶液中的三倍。然而,样本的孔隙体积差异在未观察到溶液类型之间的浸泡后。存在,在样品的情况下,水泥材料比为0.40,砂浆样本的孔结构W与水泥材料比例为0.55的样品的情况相比,溶液的pH值相比,溶液的pH值较低。这可能导致更小的浸出量的重金属。

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