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Performance investigation on RE3+(Nd3+, Er3+) dopped lithium niobate nanocrystals prepared by sol-gel technique

机译:通过溶胶 - 凝胶技术制备的RE3 +(ND3 +,ER3 +)掺杂锂铌酸纳米晶体的性能研究

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摘要

Properties of RE3+( Nd3+, Er3+) dopped lithium niobate(LN) nanocrystals prepared by sol-gel technique are investigated in this paper. The as-obtained LN nanocrystals are the only crystalline phase according to the X-ray powder diffraction (XRD) and transmission electron microscope (TEM) results The absorption and emission spectra were measured in the visible and near infrared regions, and compared with that of melt-grown LN crystals. The excitation wavelength was 514 nm and 355 nm for Er3+ and Nd3+ dopped LN nanocrystal samples, respectively A ( %v2-4hs/2) and a ( 4F3/2-4I11/2) near infrared lasing transition was measured at 1035 nm and 1077 nm in Er3+ and Nd3+ dopped LN nanocrystal samples, respectively. The results show red shifts in emission spectra in Er3+ dopped LN nanocrystal samples, and blue shifts in emission spectra in Nd3+ dopped LN nanocrystal will be also discussed in the paper.
机译:本文研究了通过溶胶 - 凝胶技术制备的RE3 +(ND3 +,ER3 +)掺杂铌酸锂(LN)纳米晶体的性质。如所获得的LN纳米晶体是根据X射线粉末衍射(XRD)和透射电子显微镜(TEM)的唯一结晶相(TEM)结果,在可见和近红外区域中测量吸收和发射光谱,并与其相比熔化的LN晶体。 ER3 +和ND3 +掺杂LN纳米晶体样品的激发波长为514nm,355nm,分别在1035nm和1077测量近红外激光转变的(%v2-4hs / 2)和近红外激光转变的(4f3 / 2-4i11 / 2) NM分别在ER3 +和ND3 +掺量的LN纳米晶体样品中。结果显示ER3 +掺杂LN纳米晶样品中发射光谱中的红色移位,并在纸上讨论了ND3 +掺杂LN纳米晶体中发射光谱中的蓝色变化。

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