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RECOVERY OF YTTRIUM AND NEODYMIUM FROM COPPER PREGNANT LEACH SOLUTIONS BY SOLVENT EXTRACTION

机译:通过溶剂萃取从铜孕浸出溶液中恢复钇和钕

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The solvent extraction of yttrium and neodymium from copper pregnant leach solutions (PLS) using Primene JM-T, a primary aliphatic amine, has been studied. Effect of contact time, pH, sulfate concentration, and extractant concentration were investigated using synthetic and actual PLS systems. Standard experimental conditions were 5 minute contact time, pH ~2.5, and 10 % v/v Primene JM-T concentration. Distribution isotherms were constructed for the pure systems and for actual copper leach solutions. Synthetic solutions contained 100 ppm Y and ~75 ppm Nd. Samples of PLS contained 2-10 ppm Nd and 14-30 ppm Y. Results showed that complete extraction of both yttrium and neodymium occurred within five minutes and at pH values greater than 1. It was also found that sulfate concentration does not inhibit extraction at any concentration. Additionally, the distribution isotherms created show that extraction for these metals can operationally take place in one stage.
机译:研究了使用PrimeNe JM-T,初级脂族胺来自铜孕浸出溶液(PLS)的钇和钕的溶剂萃取。使用合成和实际PLS系统研究了接触时间,pH,硫酸盐浓度和萃取剂浓度的影响。标准实验条件为5分钟接触时间,pH〜2.5和10%v / v丙烯JM-T浓度。为纯系统和实际的铜浸液构建分布等温线。合成溶液含有100ppm y和〜75ppm nd。 PLS样品含有2-10ppm Nd和14-30ppm y。结果表明,在五分钟内,在五分钟内发生钇和钕的完全提取,在pH值大于1.它也发现硫酸盐浓度不抑制萃取任何浓度。另外,分布等温物创建表明,这些金属的提取可以在一个阶段进行操作。

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