Adsorption or Inclusion Behavior of Polymeric Metal Complexes and Radiation Polymerization of Included Butadiene

摘要

Adsorption or inclusion behavior of small molecules to polymeric metal complexes was investigated. Polymers containing paramagnetic metalloporphyrin moieties in their side chains (5-(4-acrylamidephenyl)-10,15,20-triphcnylporphinato-metal (AATPP-M)) adsorbed oxygen, argon, and other gaseous molecules. Copper carboxylato complexes formed clathlate compounds which included butadiene, 1-propyne, and other gaseous monomer. Polymerizations of butadiene and related vinyl and diene compounds were tried by γ-ray irradiation. Although the yield of polymer was very low, high polymers were obtained from the polymerization of butadiene.