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Effect of intraparticle diffusion-reactions at reverse flow reactors.Cases study: Methane catalytic oxidation

机译:逆流反应器在逆流反应下的脑炎扩散反应的影响。研究:甲烷催化氧化

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Reverse Flow Reactor(RFR)is a fixed bed reactor whose direction of flow changes at a certain time periodically.To obtain an overview of the flow direction changing on the RFR effect on the reaction rate,the intraparticle diffusion reaction factor needs to be assessed.The flow that changes in RFR causes the value of tortuosity to behave dynamically so that the reaction rate also changes dynamically.The model approach that involves intraparticle diffusion reactions is to determine the effectiveness factor.The procedure used is to estimate the effectiveness of the simulated reaction,which allows obstacles due to intraparticle diffusion to be considered at each point of the reactor without using numerical integration of the diffusion equation in the pellet(catalyst).The results obtained show that the conversion of methane gas changes over time.This change can be approached by assuming the total reaction rate in bulk is constant,but the total reaction rate in the catalyst varies depending on the intraparticle diffusion reaction,which is indicated by the value of effectiveness factor.The dynamic effectiveness factor behaviour can be approximated by the 6th degree polynomial equation as follows: 6.38e-13*t6 + 3.23e-10*t5 - 5.84e-8*t4 + 4.34e-6*t3 - 9.91e-5*t2 -0.0004*t + 0.1781
机译:反向流量反应器(RFR)是固定床反应器,其流动方向定期在一定时间内变化。为了获得对RFR对反应速率的影响变化的流动方向的概述,需要评估粒前扩散反应因子。 RFR改变的流程导致曲折性的值动态地表现,使得反应速率动态变化。涉及粒子囊肿扩散反应的模型方法是确定有效性因素。使用的程序是估计模拟反应的有效性,这允许由于在反应器的每个点处考虑由于颗粒中的椎间内部扩散引起的障碍物,而不使用颗粒(催化剂)中的扩散方程的数值积分。结果表明甲烷气体的转化随时间变化。这一变化可以是通过假设散装中的总反应速率是恒定的,但催化剂中的总反应速率取决于o n个子体扩散反应,其由有效性的值表示。动态有效性因子行为可以通过第6度多项式方程近似,如下所示:6.38E-13 * T6 + 3.23E-10 * T5 - 5.84E- 8 * T4 + 4.34E-6 * T3 - 9.91E-5 * T2 -0.0004 * T + 0.1781

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