Ultra-High-Rate Pseudocapacitive Energy Storage in Three-Dimensional Nanoporous Gold/Silver Oxide Composites through Oxidation/Reduction of Silver(I) Oxide to Silver (III) Oxide in Non-Aqueous Electrolytes

摘要

Charge storage in pseudocapacitive materials occurs through electron transfer (i.e. faradaic current) involving oxidation and reduction reactions. This process is usually extremely fast because the reactions take place near the surface of the material, meaning the species involved diffuse over short distances. Ionic species such as H~+, OH~-, Li~+, and Na~+ commonly used to store charge in pseudocapacitive materials are usually "foreign" elements in the materials. In this talk, I will demonstrate a pseudocapacitive charge storage approach where the ionic species is part of the material. Here we use Ag~+ as the working ion in a non-aqueous electrode and silver (1) oxide grown on a three-dimensional nanoporous gold scaffold as the storage medium. Pseudocapacitive charge storage occurs through electrochemical oxidation/reduction of silver (I) oxide to silver (III) oxide at scan rates as high as 1000 mV/s. These high rates are justified by (i) the intrinsic nature of the working ion (Ag~+), which is better accommodated by the host silver oxide material as opposed to foreign ions, and (ii) the excellent electronic conductivity provided by the 3D metallic scaffold current collector.