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Two-Dimensional, Two-Phase, Non-Isothermal Model Ofproton Exchange Membrane Fuel Cell

机译:二维,两相,非等温模型的补充膜燃料电池

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Fuel cells are part of the environmental and transportation solution of our future. With the creation of new performant catalysts, the use of less noble metals in the catalyst layer and possible replacement of the Pt, it is essential to develop multiphysic models with high degree of detail for a complete optimization of the system. In this work, we develop a simple and accurate two-dimensional model for the resolution of the effects of anode and cathode flows and GDLs, catalyst layers and membrane. Brinkman equations are used to model flow distribution in GDLs and CLs. Maxwell-Stefan equations are used to model transport of gas species in GDLs and CLs by advection and diffusion mechanisms, and electrochemical reactions in the CL interfaces are modeled by modified Butler-Volmer equations. Furthemore liquid water, and dissolved water are included in the model. Conservation of liquid saturation is included in the cathode layers because of its effect on the gas transport and the cell performance due to flooding specially at high current densities. Equations are solved numerically with the commercial finite element package, COMSOL Multiphysics v5.5. Fully-coupled solution is used with Newton iterations and direct MUMPS solver.
机译:燃料电池是我们未来环境和运输解决方案的一部分。随着新的性能催化剂的创造,在催化剂层中使用较少的贵金属并可能更换PT,对于开发具有高细节的多体模型,可以完全优化系统。在这项工作中,我们开发了一种简单而准确的二维模型,用于分辨阳极和阴极流动和GDL,催化剂层和膜的影响。 Brinkman方程用于在GDL和CLS中模拟流量分布。 Maxwell-Stefan方程用于通过平凡和扩散机制模拟GDL和CLS中的气体物种的运输,并且CL界面中的电化学反应由改进的管家 - Volmer方程建模。模型中包含脱脂液水和溶解的水。液体饱和度的守恒包括在阴极层中,因为它对在高电流密度的洪水的洪水引起的气体运输和电池性能的影响。等式用商业有限元包,COMSOL Multiphysics V5.5进行了数值解决。完全耦合的解决方案与牛顿迭代和直接腮腺组求解器一起使用。

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