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Mechanistic Insights into the De-/Lithiation of Iron-Doped Zinc Oxide: From Fundamental Understanding to Practical Considerations

机译:机械洞察铁掺杂氧化锌的去/锂化:从基本上理解到实际考虑

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Owing to their unique combination of high energy and power density, lithium-ion batteries are now the state-of-the-art energy storage technology for powering small consumer electronics and increasingly also for large-scale applications like electric vehicles. Yet, especially for the latter, there is a growing need for batteries that can provide not only high energy densities, but also the possibility to be rapidly recharged. This is challenging for the currently used graphite anodes, since its low lithiation potential (~0.1 V vs. Li/Li~+) in combination with the sluggish lithium transport across the solid electrolyte interphase (SEI) and within the graphite structure can lead to lithium plating and dendrite formation during fast charging, particularly at low temperatures.
机译:由于它们独特的高能和功率密度组合,锂离子电池现在是最先进的能量存储技术,用于为小型消费电子产品供电,也可以越来越多地用于电动车辆等大型应用。 然而,特别是对于后者而言,对可以提供的电池不断增长,这些电池不仅可以提供高能量密度,而且可以快速充电的可能性。 这对目前使用的石墨阳极具有挑战,因为其低锂锂电相(〜0.1V与Li / Li〜+)与穿过固体电解质相互作用(SEI)的缓慢锂传输,并且在石墨结构中可以导致 快速充电期间锂电镀和树突式形成,特别是在低温下。

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