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Addition of Carbon Nanodots for Improving Charge/Discharge Characteristics of Lithium Metal Anode

机译:添加碳纳米蛋白,用于提高锂金属阳极的充电/放电特性

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Lithium metal is considered as the most promising anode material for high-energy-batteries due to its high theoretical capacity and low electrochemical potential. However, dendrite formation due to uncontrollable Li growth during cycling is a major challenge. Lithium dendrite growth leads to low coulombic efficiency, short cycle life, and safety issues. To solve the problem, addition of 2D carbon nano material that lead uniform Li deposition has been reported. Here, we report carbon nanodots (CND) as an electrolyte additive which can suppress dendrite growth and keep stable Li metal deposition/dissolution process. CND has defect sites and functional groups that attract Li ions and serve as a Lithiophilic nucleation site for uniform nucleation.
机译:由于其高理论能力和低电化学电位,锂金属被认为是高能电池最有前途的阳极材料。 然而,由于无法控制的锂增长导致的树突式形成是一个重大挑战。 锂枝晶生长导致库仑效率低,循环寿命短,安全问题。 为了解决问题,已经报道了引入均匀Li沉积的2D碳纳米材料。 这里,我们将碳纳多(CND)报告为电解质添加剂,其可以抑制树突生长并保持稳定的Li金属沉积/溶解过程。 CND具有吸引锂离子的缺陷部位和官能团,并用作均匀成核的锂硫醇成核位点。

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