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Highly Conductive Thermoplastic Composite Blends Suitable for Injection Molding of Bipolar Plates

机译:适用于双极板注射成型的高导电热塑性复合混合物

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This study aimed at developing highly conductive, lightweight, and low-cost bipolar plates for use in proton exchange membranes (PEM) fuel cells. Injection and compression molding of highly filled polypropylene, PP, and polyphenylene sulfide, PPS, based blends were used as a mean for mass production of bipolar plates. Loadings up to 60-wt% in the form of graphite, conductive carbon black and carbon fibers were investigated. The developed formulations have a combination of properties and processability suitable for bipolar plate manufacturing, such as good chemical resistance, sufficient fluidity, and good electrical and thermal conductivity. Electrical resistivities around 0.15 and 0.09 Ohm-cm were respectively achieved for the PP and PPS-based blends, respectively. Two bipolar plate designs were successfully fabricated by molding the gas flow channels over aluminum plates to form a metallic/polymer composite plate, or simply by direct injection molding of the conductive polymer composite. For the first design, overall plate resistivities of 0.2 and 0.1 Ohm-cm were respectively attained using PP and PPS based blends as conductive skin. A lower volume resistivity of around 0.06 Ohm-cm was attained for the second injected plate design with PPS based blend.
机译:本研究旨在开发高导电性,重量轻且低成本的双极板在质子交换膜(PEM)燃料电池中使用。注射和压缩高度填充的聚丙烯,PP,和聚苯硫醚,PPS的成型,基于共混物用作用于大规模生产的双极板的平均值。负荷高达石墨形式60重量%,导电性炭黑和碳纤维进行了研究。发达制剂具有性能和加工性能适合双极板制造,如良好的耐化学性,充分的流动性,和良好的电和热传导性的组合。围绕0.15和0.09欧姆·厘米的电阻率分别为基于PPS-PP和共混物分别实现。两个双极板设计成功地被模压在铝板的气体流动通道以形成金属/聚合物复合材料板,或简单地通过直接注射导电性聚合物复合材料的模制制造。对于第一个的设计,为0.2和0.1欧姆 - 厘米整体板的电阻率是使用基于PP和PPS的共混物作为导电性皮肤分别实现。的周围被获得用于第二0.06欧姆 - 厘米的较低体积电阻率注入板设计与基于PPS共混物。

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