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Using Thiosulphate as Gold Leaching Agent in a Brazilian Carbonaceous Ore: Batch Tests Analysis

机译:在巴西碳质矿石中使用硫代硫酸盐作为金色浸出剂:批量试验分析

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Although cyanidation, as a hydrometallurgical route for gold ores, is well consolidated in theindustry, its environmental implications and specific demands have driven the development ofseveral studies on the use of alternative leaching agents. The use of thiosulphate has been studiedsince the 1980's, having occurred in 2014, the first commercial application at Barrick GoldCorporation (USA).The main motivation for this process is the low affinity of thiosulphate withcarbonaceous ores, avoiding the preg-robbing effect characteristic of cyanidation. In this sense, theobjective of the present study is to evaluate the performance of thiosulphate as a gold leaching agentfor a Brazilian carbonaceous ore. A sample of the ore was homogenized, splitted and submitted tochemical and mineralogical characterization and leaching tests with thiosulphate and to cyanidation.The dosages of thiosulphate and auxiliary chemicals (copper sulphate, ammonia, sodium sulphite)were optimized and the best results were compared with cyanidation (typical industrial dosage). Theleaching times in both processes were also evaluated. The best result was 74.8 % gold extraction in 6hours, with dosages of 60 kg/tore ammonium thiosulphate, 38 kg/tore ammonium, 1 kg/tore coppersulphate and 1.5 kg/tore sodium sulphite. This result is higher than with cyanidation in typical dosageand 8 hours (20.4 %), which is possible due preg-robbing effect. This demonstrates the potential ofthiosulphate's technical viability as an alternative to cyanidation.
机译:虽然氰化是金矿的湿法冶金途径,但在工业中巩固,其环境影响和特定要求推动了对使用替代浸出剂的使用研究。硫代硫酸盐的使用已经研究了20世纪80年代,于2014年发生,是Barrick Goldcorporation(美国)的首次商业申请。该过程的主要动机是硫代硫酸盐的矿物质的低亲和力,避免了氰化的预抢夺效果特征。从这个意义上讲,本研究的目的是评估硫代硫酸盐作为巴西碳质矿石的金浸出剂的性能。矿石样品均质化,分离和提交具有硫代硫酸盐和氰化物的化学和矿物学表征和浸出试验。优化了硫代硫酸盐和辅助化学品(硫酸铜,氨,亚硫酸钠)的剂量,并将最佳结果与氰化物进行了比较(典型的工业剂量)。还评估了两种过程中的时间。最佳结果为74.8%的金萃取在6小时内,剂量为60kg /灰硫代硫酸铵,38kg / tore铵,1kg /撕裂烯烃和1.5kg / tore亚硫酸钠。该结果高于典型Dosageand 8小时(20.4%)的氰化,这是可能的预抢夺效果。这证明了硫酸化的技术可行性的潜力作为氰化的替代品。

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