首页> 外文会议>Biennial Meeting (Hauptversammlung) of the Kolloid-Gesellschaft in conjunction with the Bayreuth Polymer Symposium >Mechanical, structural and thermodynamic properties of confined self-assembling systems
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Mechanical, structural and thermodynamic properties of confined self-assembling systems

机译:狭窄的自组装系统的机械,结构和热力学性能

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Systems in which amphiphilic particles (surfactants, lipids, block-copolymers) can self-assemble into mono- or bilayers form variety of stable and metastable structures on the nanometer length scale. In the ordered structures (lamellar, hexagonal and cubic phases) the translational and rotational symmetries are broken. For this reason the geometrical and chemical properties of the confining surfaces have a particularly strong effect on such systems. We study lamellar and cubic phases in oil-water-surfactant mixtures within a generic semi-microscopic model, using a mean-field approximation. We focus on those effects of confinement which in simple fluids are absent; one example is a switch of a lamellae orientation when the wall separation is varied. We show how the structural changes of the confined fluid are reflected in the measurable solvation force between the confining walls and in phenomena analogous to capillary condensation. We emphasize those effects of confinement which might be important for potential applications.
机译:其中两亲颗粒(表面活性剂,脂质,嵌段共聚物)可以自组装成单级或双层,在纳米长度尺度上形成各种稳定和稳定的结构。在有序结构(层状,六边形和立方相)中,翻译和旋转对称性被破坏。因此,限制表面的几何和化学性质对这种系统具有特别强烈的影响。我们使用平均场近似研究通用半导体模型内的油水 - 表面活性剂混合物中的层状和立方相。我们专注于那些在简单的液体中的限制的影响;一个示例是当壁分离改变时的薄片取向的开关。我们展示了狭窄流体的结构变化如何反映在限制壁和类似于毛细血管缩合的现象之间的可测量溶剂化力。我们强调了对潜在应用可能是重要的限制影响。

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