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TECHNOLOGY FOR EFFICIENT FLUIDIZED BED COMBUSTION OF PETROLEUM COKE IN THE FORM OF COAL-WATER SLURRY

机译:高效流化床燃烧石油冰块的技术

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Today oil refineries in Russia have accumulated large amounts of petroleum coke (petcoke). High content of sulphur, vanadium, nickel and other metals, poor free-running properties, low volatile content in this fuel make its burning via conventional methods rather complicated, and thus, limit its application in the energy sector. To ensure efficient use of petroleum coke in the energy sector, a special technology has been developed for efficient combustion of petroleum coke in a fluidized bed in the form of cavitation coal-water slurry (CCWS). Specific character of petroleum coke as a fuel, namely its low reactivity, significant levels of sulphur and vanadium, high corrosion and slagging properties, define methods and devices for its use in the energy sector. The most common methods used throughout the world for petroleum coke combustion are those for combustion in fluidized bed boilers when sorbent agent is injected into the furnace to fix sulphur and mixed with coal in coal-fired boilers equipped with an efficient desulfurization system. A promising, though a very expensive method, is the application of petroleum coke in an integrated gasification combined cycle (IGCC). It is possible to burn "pure" petroleum coke in conventional coal-fired furnaces of dedicated design suitable for firing low-reactivity coals, this method being not widely spread, though. Typically, these furnaces may be blanketed high-forced combustion chambers, down-shot furnaces or slag-tap furnaces with intermediate bins, with increased height of furnace chamber, high-temperature (up to 400oС) hot air heating and finely ground coal dust in bowl or ball-and-tube mills. Russia has not seen a wide application of petcoke in the energy sector. Some power plants carried out pilot combustion of petroleum coke mixed with coal. These tests, however, have not resulted in a permanent application of petcoke by these power plants. Pilot combustion and studies when petroleum coke was burned in a fluidized bed as CCWS showed the possibility to ensure its stable combustion and good environmental performance. This result matches with global experience aimed at combustion of petcoke in FB boilers, including CFB boilers. In order to study the possibility to introduce the technology of combustion of petcoke as a cavitation coal-water slurry (CCWS) in the furnace of utility oil-and-gas-fired boiler Е-500-140ГМН (ТГМЕ-464), there were computational and analytical studies carried out and boiler modification design developed in one of the Russian power plants. The application of fluidized bed technology allows involving in the balance 750-850 thousand t/year of petroleum coke for modification of 3 boilers.
机译:如今,俄罗斯的石油炼油厂积累了大量的石油焦炭(佩皮克)。高含量的硫,钒,镍等金属,可差的自由运行性能,这种燃料中的低挥发性含量使其通过常规方法燃烧而变得相当复杂,因此限制了其在能量领域的应用。为了确保有效地利用石油焦炭在能源领域,已经开发了一种特殊的技术,以便以空化煤水浆(CCWS)的流化床中的石油焦炭有效燃烧。石油焦炭的特定特征作为燃料,即其低反应性,显着水平的硫和钒,高腐蚀和脱渣性能,定义了在能量领域中使用的方法和装置。在整个世界各地用于石油焦炭燃烧中的最常见方法是当吸附剂注入炉中以固定硫磺和配备有效的脱硫系统的燃煤锅炉中混合煤的流化床锅炉中的燃烧。虽然具有非常昂贵的方法,但是在综合气化组合循环(IGCC)中的应用是一种很有希望的石油焦。可以在适用于烧制低反应性煤的传统燃煤炉中燃烧“纯”石油焦炭,这种方法不广泛传播。通常,这些熔炉可以是覆盖的高强制燃烧室,下射炉或具有中间箱的炉渣挖掘炉,具有增加的炉室高度,高温(最多400次)热空气加热和精细粉煤粉尘碗或球管铣刀。俄罗斯在能源领域没有看到佩德科克广泛应用。一些发电厂进行了与煤混合的石油焦的试验燃烧。然而,这些测试没有导致这些发电厂永久地应用PETCOKE。当CCWS显示有可能确保其稳定的燃烧和良好的环境性能时,当石油焦炭在流化床中燃烧时的试验燃烧和研究。这结果与全球经验相匹配,旨在剥落在FB锅炉中的剥离,包括CFB锅炉。为了研究剥落煤水浆料(CCWS)在公用事业油燃气锅炉炉中燃烧燃烧技术的可能性,有500-140гмн(Тгме-464),有在俄罗斯发电厂之一开发的计算和分析研究和锅炉改造设计。流化床技术的应用允许涉及750-850万吨/年的石油焦炭进行修改3锅炉。

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