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Study on the Impact of Core Wettability and Oil Saturation on the Rheological Behavior of CO2-Foams

机译:核心润湿性和油饱和对CO2 - 泡沫流变行为的影响研究

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Foam processes aim to improve the efficiency of gas-based injection methods through gases mobility control. They have been successfully applied in various EOR contexts: CCUS through CO2-EOR, steam injection for heavy oil reservoirs, and also in fractured reservoirs. The success of such processes depends on multiple factors, among which the interactions between the surfactants, the oil and the rock, play a key role. The purpose of this study is to provide initial answers by focusing on the influence of wettability and oil saturation on the behavior of CO2-foam flows. A new coreflooding set-up is designed for ‘mesoscopic’ cores (2.5 cm diameter) in order to conduct foam formulation screening and perform faster foam injection tests at reservoir conditions (up to 200 bar and 60 °C). This set-up was first validated by repeating experiments performed previously on classical corefloods with 4 cm diameter cores. Similar results in terms of mobility reduction were obtained for the same operating conditions with a considerable reduction of test duration. All experiments were performed with Clashach sandstones cores having approximatively 16 % porosity and 600 mD permeability. Two gas compositions have been studied: (1) a dense supercritical CO2 (density of 638 kg/m3 at P = 160 bar, T = 60°C) and (2) a non-dense gas mixture of CO2 and CH4. For each gas composition, four foam injection tests were carried out: two on water-wet rock samples, two others on crude- aged core samples, and for both in the absence and in presence of oil. Anionic surfactant formulations and gas were co-injected with a gas fraction of 0.7. Foam rheology was assessed by measuring foam apparent viscosity through a scan of interstitial velocities. All the tests performed in dense conditions have highlighted the generation of strong foams, which present shear-thinning rheological behavior; the apparent viscosity decreases as a power law of the interstitial velocity. An influence of the wettability is observed on the foam apparent viscosity, which drops off by 30 % in altered wettability rock samples. When samples were originally saturated with oil at Swi, the level of apparent viscosity remains globally unchanged but the kinetics of the initial formation of the foam is slower with oil than without. Foam flooding experiments are sometimes carried out simply in the presence of oil without taking into account the influence of wettability, which appears to be as important, if not more, than the oil saturation itself. These results will hopely provide some guidance for future foam studies and raise awareness on the importance of these parameters.
机译:泡沫工艺旨在通过气体迁移率控制提高气体注射方法的效率。它们已成功应用于各种EOR语境:CCU通过CO2-EOR,蒸汽注射为重油储层,以及裂缝储层。这些过程的成功取决于多种因素,其中表面活性剂,油和岩石之间的相互作用起着关键作用。本研究的目的是通过专注于润湿性和油饱和对CO2 - 泡沫流动的影响来提供初始答案。一种新的CorePlood Setum设计用于'介镜'芯(直径2.5厘米),以便在储层条件下进行泡沫配方筛选,并在储层条件下进行更快的泡沫注射试验(最多200巴和60°C)。首先通过重复先前在具有4cm直径核心的经典内核污水上进行的实验进行验证的该设置。对于相同的操作条件,获得了相同的操作条件的迁移率降低的类似结果。用具有近似16%孔隙率和600md渗透性的Clashach砂岩芯进行所有实验。已经研究了两种气体组合物:(1)(1)致密的超临界CO 2(P = 160巴的密度为638kg / m 3,T = 60℃)和(2)CO 2和CH4的非致密气体混合物。对于每种气体组成,进行了四次泡沫注射试验:两个在水湿岩样上,另外两种核心样品,以及在不存在和存在的情况下。共注入阴离子表面活性剂配方和气体,气体分数为0.7。通过通过扫描间质速度测量泡沫表观粘度来评估泡沫流变学。在密集条件下进行的所有测试都突出了强泡沫的产生,目前剪切稀疏流变行为;表观粘度作为间质速度的动力法降低。在泡沫表观粘度下观察到润湿性的影响,其在改变的润湿性岩石样品中滴下30%。当样品最初用油脂饱和时,表观粘度的水平仍然不变,但泡沫初始形成的动力学与油较慢。泡沫洪水实验有时在油的存在下仅在没有考虑润湿性的影响,这似乎与油饱和本身一样重要。这些结果将为未来的泡沫研究提供一些指导,并提高对这些参数的重要性的认识。

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