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AMMONIA LEACHING RESEARCH OF EAF DUSTS AFTER WEALZ-PROCESS

机译:威尔兹工艺后氨浸出研究

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An efficient technology is currently being searched for the processing of electric arc furnace (EAF) steelmaking dust obtained at the Ural steelmaking plants. In this study, the hydrometallurgical processing of electric arc furnace dusts after Wealz process was investigated on a laboratory scale under normal temperature and pressure conditions. The Waelz-fume is the following chemical composition: 61 wt% Zn, 10 wt% CI, 6 wt% Pb, 1 wt% Fe, 1 wt% K. The most optimal for hydrometallurgical processing are ammonia solutions, which allow to transfer zinc into the solution while lead and iron ought to remain as a solid residue. During the process complicated chemical reactions proceed with the zinc complex compounds formation resulting from the interaction between Zn~(2+), CI- ions and NH_3 ligands depending on the pH value. Therefore, this method does not require the introduction of additional purification stages from chlorine and fluorine ions, which make processing difficult, since their accumulation can lead to difficulty in stripping cathode zinc.The zinc behavior under the influence of ammonium chloride with ammonium as the leaching agents was discussed. Based on the obtained data plots were built and the dependence between the ratio liquid-solid (LIS), ammonium chloride and ammonium concentration were investigated. Optimal leaching parameters were determined. The possibility of zinc electroextraction from the ammonium solutions with obtained cathode zinc was studied.
机译:目前正在寻找高效的技术,用于在撒拉炼钢厂获得的电弧炉(EAF)炼钢灰尘的处理。在该研究中,在常温和压力条件下,在实验室规模上研究了Wealz工艺后电弧炉粉尘的液压冶金加工。 Waelz-fume是以下化学成分:61wt%Zn,10wt%Ci,6wt%Pb,1wt%Fe,1wt%K.对于氨溶液的最佳最佳溶液是氨溶液,其允许转移锌在铅和铁应该保持固体残留物中进入溶液中。在过程中,复杂化学反应与Zn〜(2+),Ci-ince和NH_3配体之间的相互作用取决于pH值,进行锌复合化合物形成。因此,该方法不需要引入来自氯和氟离子的额外净化阶段,这使得加工难以使其累积能够导致剥离阴极锌的困难。氯化铵与铵作为浸出的氯化铵的影响。代理商讨论过。基于所获得的数据图,研究了比率液固(LIS),氯化铵和铵浓度之间的依赖性。确定了最佳浸出参数。研究了用得到的阴极锌的铵溶液锌电催化的可能性。

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