Insight into living crystallization-driven self-assembly of chargeterminatedpoly(3-hexylthiophene) homopolymers into uniformnanofibers based on the energy landscape

摘要

Control over self-assembly approaches to well-defined crystalline 1D nanostructures isa significant for applications in optoelectronics and biomedicine.Living crystallization-drivenself-assembly (CDSA) allows the precision synthesis of crystalline micelles with controlledsize1,2.Living CDSA has been applied wide range of crystallizable polymers,such aspoly(ferrocenylsilane) (PFS),oligo(p-phenylenevinylene) (OPV),and poly(di nhexylfluorene)(PF).