Development of new synthetic methodologies for metalnanoparticle/MOF hybrids

摘要

Metal-organic frameworks (MOFs) or porous coordination polymers (PCPs) are newtypes of porous materials composed of metal ions and organic ligands.Unlike toconventional porous materials such as zeolite and mesoporous silica,their porous propertiescan be more easily designed by judicious choice of metal ions and organic linkers1.Untilnow,countless numbers of MOFs have been synthesized as host materials not only for gasmolecules2 but also for other bigger compounds such as organic dyes3,polymers4,metalnanoparticles5 and so on to obtain functional composites.