Magnetic Properties Based on Structural Phase Transition in Alkylated Cobalt(II) Complexes

摘要

Spin transition (ST) phenomena in bis-terpyridine Co(II) derivatives having been widely investigated, in part due to their ease of modification. The generation of a HS species induced via intermolecular interactions between bound modified terpyridine ligands is expected to show enhanced magnetic anisotropy because of the resulting distorted coordination environment of Co(II) ion.