Adsorption of acetic acid from dilute solution on zeolite 13X: Isotherm, kinetic and thermodynamic studies

摘要

The adsorption behavior of acetic acid on zeolite 13X was studied at 25°C, 35°C and 45°C in a batch experiment. Experimental data were applied to pseudo-first-order and pseudo-second-order adsorption kinetic models, and tested against Langmuir and Freundlich isotherms. Thermodynamic parameters (AG, AH and AS) of adsorption were also calculated. The data fit the pseudo-second-order kinetic model and Freundlich isotherm well. The calculated values of AG, AH and AS indicate that the adsorption is spontaneous and endothermic; it causes an increased extent of randomness at the solid-solution interface.