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CLATHRATE HYDRATE INHIBITION BY HYDROPHOBIC NANOPARTICLES AT HYDRATE- WATER INTERFACES

机译:疏水纳米颗粒在水合物界面的疏水抑制

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As the crude oil and gas resources are depleted,a growing number of harvests require exploration of the world’s remote locations with harsh conditions including off-shore reservoirs.The low-temperature and high- pressure conditions at many of these reservoirs provide ideal environments for the formation of clathrate or gas hydrates.The flow assurance issue arising from the formation of hydrates inside the extraction pipeline imposes serious impedance to the continuous off-shore production and operation.Thus, research in the petroleum industry had been focused on inhibiting the formation of gas hydrates.Past works mainly concerned about the injection of bulk thermodynamic inhibitors such as alcohol and glycols to shift the thermodynamic equilibrium and recent works have explored the application of a small amount of kinetic inhibitors such anti-agglomerants and imides to the oil/gas pipe line.As one of kinetic inhibitors,this work employs hydrophobic silica nanoparticles at interfaces of hydrate and water and will present hydrate growth behaviors.
机译:随着原油和天然气资源耗尽,越来越多的收获需要探索世界上的遥控器,包括偏离岸上的水库。许多这些水库的低温和高压条件都提供了理想的环境形成裂土或天然气水合物的形成。萃取管道内部水合物形成的流动保证问题对连续的离岸生产和运作产生严重阻抗。本,石油工业的研究一直专注于抑制气体的形成水合物主要涉及批量热力学抑制剂的注射,例如醇和二醇转移热力学平衡和最近的作品已经探索了少量动力学抑制剂这种抗聚合物和酰亚胺的抗聚合物和含有油/气管管线。动力学抑制剂之一,这项工作在界面采用疏水性二氧化硅纳米粒子水合物和水并将呈现水合物生长行为。

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