Preconcentration of Arsenic in Radix aucklandiae by Sulfhydryl Cotton and Determination by Atomic Fluorescence Spectrometry

摘要

Using sulfhydryl cotton for preconcentration of arsenic in Radix aucklandiae and determination of the arsenic by hydride generation-atomic fluorescence spectrometry. The samples were pretreated by high pressure digest. The experimental conditions such as negative high-voltage of instrument, preconcentration conditions and separation conditions of arsenic were studied and optimized. There was a good linear relationship between the fluorescence intensity and arsenic concentration in the range of 0-10μg/L with a correlation coefficient of 0.9997, while the detection limits was 0.06μg/L, and the relative standard deviation was 1.7%. The content of arsenic in the samples was 68.9-252.3μg/kg and the recovery was 90.0-95.0%.