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Hybrid Composites from Wheat Straw, Inorganic Filler and Polypropylene: Water Absorption and Thermal Expansion Properties

机译:来自麦秸,无机填料和聚丙烯的杂种复合材料:吸水和热膨胀性能

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A growing demand in low thermal expansion and water uptake for structural wood plastic composites (WPCs) have recently appeared in applications such as curved structure design, where minimum dimension movement and water absorption are required. Thus, thermal expansion and water absorption caused by external environment variations have to be taken into account in the design of WPCs for final application. The values of linear coefficient of thermal expansion (LCTE) for wood (or grain) and mineral (e.g., calcium carbonate) fillers are about 20 times lower than those of plastics and about 10 times lower than those of WPCs. We have studied thermal and mechanical properties of wood flour (WF) and talc filled high density polyethylene (HDPE) composites1,2. The addition of WF and WF-talc mixture into neat HDPE resulted in some decreases in the glass transition and crystallization temperatures of the composites. Hybrid bio-composites from talc, WF, and polyhydroxybutyrate-co-valerate (PHBV) were analyzed by Singha et al 3. A 36% decrease of LCTE and an improvement in heat deflection temperature of the hybrid composite were also observed. To enhance the properties of WPCs, Hisashi et al4 improved water-repellent property of wood. The results suggest that the addition of SiO2 into wood-inorganic composites had a positive effect on water-repellent property.
机译:最近出现了结构木质塑料复合材料(WPC)的低热膨胀和水吸收中不断增长的需求,如弯曲结构设计,其中需要最小尺寸运动和吸水性。因此,在最终应用的WPC设计中,必须考虑由外部环境变化引起的热膨胀和吸水性。木材(或谷物)和矿物质(例如,碳酸钙)填料的线性膨胀(LCTE)的线性系数值约为塑料的20倍,比WPC的塑料低约10倍。我们研究了木粉(WF)和滑石填充的高密度聚乙烯(HDPE)Composites1,2的热和力学性能。将WF和WF-TALC混合物加入整齐的HDPE中导致复合材料的玻璃化转变和结晶温度的一些降低。通过Singha等人分析来自滑石,Wf和多羟基丁酸酯 - 共律(PHBV)的杂化生物复合材料3.16%的LCTE减少,并且还观察到杂化复合材料的热偏转温度的提高。为了增强WPC的性质,Hisashi等,改善了木材的防水性。结果表明,将SiO 2加入木材无机复合材料对防水性质具有积极影响。

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